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Update on High-Temperature Superconductivity in B-doped Q-Carbon

May 17th, 2018

Researchers at North Carolina State University have significantly increased the temperature at which carbon-based materials act as superconductors, using a novel, boron-doped Q-carbon material.

The previous record for superconductivity in boron-doped diamond was 11 Kelvin, or -439.60 degrees Fahrenheit. The boron-doped Q-carbon has been found to be superconductive from 37K to 57K, which is -356.80°F.

"Going from 11K to 57K is a big jump for conventional BCS superconductivity," says Jay Narayan, the John C. Fan Distinguished Chair Professor of Materials Science and Engineering at NC State and senior author of two papers describing the work. BCS refers to the Bardeen-Cooper–Schrieffer theory of superconductivity.

Regular conductive materials conduct electricity, but a lot of that energy is lost during transmission. Superconductors can handle much higher currents per square centimeter and lose virtually no energy through transmission. However, superconductors only have these desirable properties at low temperatures. Identifying ways to achieve superconductivity at higher temperatures - without applying high pressure - is an active area of materials research.

To make the boron-doped Q-carbon, the researchers coat a substrate with a mixture of amorphous carbon and boron layers. The mixture is then hit with a single laser pulse lasting for only a few nanoseconds. During this pulse, the temperature of the carbon is raised to 4,000 Kelvin and then rapidly quenched.

"By incorporating boron into the Q-carbon we eliminate the material's ferromagnetic properties and give it superconductive properties," Narayan says. So far, every time we have increased the amount of boron, the temperature at which the material retains its superconductive properties has increased.

“This process increases the density of carrier states near the Fermi level,” relative to boron-doped diamond, Narayan says.

“The materials advance here is that this process allows a boron concentration in a carbon material that is far higher than would be possible using existing equilibrium methods, such as chemical vapor deposition,” Narayan says. “Using equilibrium methods, you can only incorporate boron into Q-carbon to 2 atomic percent – two out of every 100 atoms. Using our laser-based, non-equilibrium process, we’ve reached levels as high as 50 atomic percent.”

That higher concentration of boron is what gives the material its superconductivity characteristics at a higher temperature. Q-carbon is also significantly harder than diamond, as hardness and high-temperature superconductivity are directly linked through Debye frequency.

“Our findings have been reproduced by Marvin Cohen's group at Berkeley (theoretically), and ORNL and Ga Tech/NYU groups (experimentally),” Narayan says.

“We plan to optimize the material to increase the temperature at which it is superconductive,” Narayan says. “And we think we’re on the right track to reach room-temperature superconductivity. “This breakthrough in high-temperature superconductivity of Q-carbon is scientifically exciting with a path to room temperature superconductivity in novel strongly-bonded, light-mass materials. The superconductivity in Q-carbon has special significance for practical applications, as it is transparent, superhard and tough, biocompatible, erosion and corrosion resistant. Nothing like that exists today," according to University Professor Marvin Cohen of UC, Berkeley.

The most recent paper, "Progress in Q-carbon and related materials with extraordinary properties" is published in the Materials Research Letters. Earlier papers, "Q-carbon harder than diamond", is published in the MRS Communications. "High-Temperature Superconductivity in Boron-doped Q-Carbon,", and "Discovery of High-Temperature Superconductivity (Tc = 55 K) in B-Doped Q-Carbon" are published in the ACS Nano.

This material is based upon work supported by the National Science Foundation under Grant No. (NSF DMR-1735695 &1560838). NC State has filed for the U.S. patent for this technology. https://www.mse.ncsu.edu/news/high-temperature-supercondicity-in-doped-qcarbon

North Carolina State University